In normal conditions, this is almost impossible. You can't just build a wall around an electron to limit its movement, and there is an inherent uncertainty about its position anyway. A better explanation would require concepts from quantum mechanics, but it wouldn't be an ELI5 anymore.
In very extreme conditions, like the collapsing core of a supernova explosion, electrons are squeezed really really hard between the nuclei. In this case they can enter a nucleus, fuse with a proton and turn it into a neutron. The entire core of the star becomes a ball of neutrons, also known as a neutron star. This is the densest object that can exist, short of collapsing even further into a black hole.